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Which of the following statements regarding how gases occupy container volumes is NOT correct?


A) Gases fill the entire volume of a container regardless of pressure.
B) The pressure exerted by a sample of gas in a container at a given temperature is uniform in all directions.
C) As the temperature decreases, the fraction of the container volume occupied by gas molecules decreases.
D) The volume unoccupied by gas molecules is spread uniformly throughout the container volume.
E) If gases confined to a smaller volume are allowed to enter a larger volume, they expand and distribute evenly throughout the new space available.

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What is the molar mass of a gas that has a density of 3.123 g/L at STP?


A) 69.96 g/mol
B) 38.05 g/mol
C) 77.38 g/mol
D) 25.96 g/mol
E) 70.89 g/mol

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The atmospheric pressure in the eye of a hurricane is found to be 26.6 inches of mercury, which is equivalent to


A) 760 mmHg.
B) 1.00* 105 Pa.
C) 0.889 atm.
D) 0.987 bar.
E) 0.785 atm.

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Tungsten hexafluoride is one of the heaviest gases known, with a molar mass of 297.9 g/mol.At a given temperature, how long will it take WF6 to cover the distance H2 can travel in 25 seconds?


A) 304 s
B) 60.7 s
C) 51.5 s
D) 2.06 s
E) 3690 s

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In a fixed-volume container at 25 °\degree C, NO2 gas partially combines to form N2O4 gas.The mass percentage of N2O4 in the resulting mixture is 76.3%, and the total pressure is 0.500 atm.What is the partial pressure of N2O4?


A) 0.619 atm
B) 0.382 atm
C) 0.192 atm
D) 0.309 atm
E) 0.119 atm

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Calcium carbonate 100.1 g/mol) decomposes according to the following reaction: CaCO3 (s) \rightarrow CaO(s) +CO2 (g) What pressure of CO2 gas will form in a 25.0 mL jar containing 5.00 g of CaCO3 at 300 K if 0.00500% of the solid decomposes?


A) 0.246 atm
B) 2.46 atm
C) 1.00 atm
D) 2.46 * 103 atm
E) 2.46 * 10-3 atm

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Which of the following statements regarding Graham's law of effusion is correct?


A) Effusion refers to the escape of a gas through a small hole into a region of lower pressure.
B) Gases at higher densities will effuse more rapidly.
C) If the molar mass doubles, the effusion rate doubles.
D) The effusion rate of helium is five times that of neon.
E) The effusion rate of n moles of argon in a 20 L container at 20 °\degree C is 10 times that observed with a 2 L container.

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A sample of gas at 475.0 °\degree C is allowed to cool at constant volume until its pressure is one-fifth of its original value.What is the final temperature of the gas?


A) (-50.67 °\degree C)
B) 95.00 °\degree C
C) 273.2 °\degree C
D) 149.6 °\degree C
E) (-123.5 °\degree C)

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An unknown gas held in a 25.0 mL flask at 45 °\degree F exerts a pressure of 25 mtorr.By using this information with the ideal gas law, it is possible to determine


A) the mass of the gas in the container.
B) the identity of the gas in the container.
C) the number of molecules of the gas in the container.
D) the molecular geometry of the gas in the container.
E) nothing more about the gas.

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_____is how gases spread among each other; ____is how gases escape through a hole in a container.


A) Diffusion; effusion
B) Effusion; diffusion
C) Effusion; effusion
D) Diffusion; diffusion

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Which of the following gases would you expect to have the largest van der Waals a constant value?


A) Cl2
B) Ar
C) CH4
D) F2
E) Kr

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The pressure gauge on a cylinder used to fill balloons with helium shows a pressure of 1275 psi at a temperature of 25.00 °\degree C.Assuming the cylinder has a volume of 10.0 L, how many grams of helium does the cylinder contain?


A) 521 g
B) 142 g
C) 6.70 * 10 -4 g
D) 37.0 g
E) 4.00 g

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How many moles of an ideal gas are in a 7.50 *102 mL flask at 2.50 *102 torr and 37.5 °\degree C?

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9.68 * 10<...

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A sample of gas at -15.0 °\degree C is heated in a constant-volume container until the pressure is 65.0% higher than its original value.What is the final temperature of the gas?


A) 153 °\degree C
B) 426 °\degree C
C) 202 °\degree C
D) 124 °\degree C
E) 298 °\degree C

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Which of the following statements is NOT correct?


A) An increase in temperature causes an increase in pressure of a gas because the frequency of molecules colliding with the walls of the container increases.
B) An increase in temperature causes an increase in pressure of a gas because the average force exerted by molecules colliding with the walls of the container increases.
C) All gases behave like ideal gases at sufficiently low pressures and high temperatures.
D) The ratio PV/nRT for a real gas can be less than 1 because of attractive forces between molecules.
E) The pressure exerted by oxygen molecules is greater than the pressure exerted by nitrogen molecules in a balloon filled with air because oxygen molecules are heavier.

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Which of the following is NOT true?


A) P, V, T, and n for an ideal gas are state functions.
B) The ideal gas equation is PV = nRT, where R is the universal gas constant.
C) STP refers to 273 K and 1 bar, as defined by IUPAC.
D) The molar volume of a gas is the volume that one mole of an ideal gas occupies at STP.
E) The ratio PV/T has a constant value.

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You wish to measure the extent of reaction by monitoring pressure changes.Suppose 1.000 atm of tungsten hexafluoride gas at 400.00 °\degree C in a 20.0 L deposition chamber partially decomposes to form tungsten metal and fluorine gas.The products of the reaction at this point are cooled to 25.00 °\degree C.The resulting pressure, which is due to the sum of the pressures of F2 and leftover WF6, is 1.028 atm.What is the pressure due to the unreacted WF6? WF6 (g) \rightarrow W(s) + 3 F2 (g)


A) 0.3395 atm
B) 0.6605 atm
C) 0.9830 atm
D) 0.1230 atm
E) 0.1504 atm

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The density of a pure gas at STP depends on its


A) molar mass.
B) concentration.
C) temperature.
D) volume.
E) pressure.

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A sample of argon gas at 2.90 atm and 35.0 mL is heated from 20.0 °\degree C to 50.0 °\degree C.If the pressure remains constant, what is the final volume of the gas?


A) 38.6 mL
B) 87.5 mL
C) 31.8 mL
D) 35.0 mL
E) 52.5 mL

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A 5.00 L diving tank is filled to a pressure of 35.2 atm with He, then filled to a pressure of 44.8 atm with N2, and then topped off with O2 to a total pressure of 50.0 atm.What are the mole fractions of helium, nitrogen, and oxygen in the tank?

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XHelium =...

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