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Which of the following elements has the greatest electron affinity (largest positive value) ?


A) Mg
B) Al
C) Si
D) P
E) S

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If the radius of atom X is greater than the radius of atom Y, then it is also likely that


A) X has a larger electron affinity than Y does.
B) X has a larger effective nuclear charge than Y does.
C) X has greater metallic character than Y does.
D) X has a larger first ionization energy than Y does.
E) X is a poorer conductor of electricity than Y when in the solid state.

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Which of the following is the electron configuration of a sulfide ion?


A) [Ne]3s23p4
B) [Ne]
C) [Ne]3s23p1
D) [Ar]
E) [Ne]3s23p2

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D

As opposed to early periodic tables based on the law of octaves, modern periodic tables arrange the elements in order of increasing


A) nuclear binding energy.
B) number of neutrons.
C) atomic mass.
D) atomic number.
E) atomic size.

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Electron affinity is always a positive quantity.

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The first ionization energy of mercury is 1006 kJ/mol. The energy change for the reaction Hg(l) \rarr Hg+(g) + e- is therefore


A) 1006 kJ/mol.
B) greater than 1006 kJ/mol.
C) less than 1006 kJ/mol.
D) is equal to the electron affinity of mercury.
E) is equal to the second ionization energy of mercury.

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The alkali metal elements are found in _______ of the periodic table.


A) Group 1A
B) Group 2A
C) Group 3A
D) Period 7
E) Period 1

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Which of the atoms listed below has the smallest radius?


A) Al
B) P
C) As
D) Te
E) Na

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Which of the following ground-state ions has unpaired electrons?


A) P3-
B) V5+
C) Mg2+
D) Sc2+
E) S2+

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The successive ionization energies of a certain element are I1 = 589.5 kJ/mol, I2 =1145 kJ/mol, I3= 4900 kJ/mol, I4 = 6500 kJ/mol, and I5 = 8100 kJ/mol. This pattern of ionization energies suggests that the unknown element is


A) K.
B) Si.
C) As.
D) Ca.
E) S.

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D

Which of the following elements behaves chemically similarly to silver?


A) nickel
B) gold
C) sulfur
D) chlorine
E) iron
F) beryllium

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Consider the following reaction: 3Li + Z \rarr Li3Z. What is the formula for the compound if we substitute magnesium for lithium?


A) MgZ
B) Mg2Z
C) MgZ2
D) Mg3Z
E) Mg3Z2

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In a surprisingly large number of their properties, beryllium resembles aluminum and boron resembles silicon. Such a relationship is called


A) amphoterism.
B) an allotropic relationship.
C) a diagonal relationship.
D) the periodic law.
E) an isoelectronic series.

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Which of the following elements has the greatest metallic character?


A) Br
B) F
C) Ge
D) Mn
E) Sc

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Which of the following make an isoelectronic pair: Cl- , O2-, F, Ca2+, Fe3+?


A) Ca2+ and Fe3+
B) O2- and F
C) F and Cl-
D) Cl- and Ca2+
E) None of the above.

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The law of octaves states that every eighth element has similar properties when arranged in order of increasing


A) nuclear binding energy.
B) number of electrons.
C) number of neutrons.
D) atomic mass.
E) atomic number.

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D

For phosphorus atoms, which ionization energy will show an exceptionally large increase over the previous ionization energy?


A) 2nd
B) 3rd
C) 4th
D) 5th
E) 6th

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Arrange the following ions in order of decreasing ionic radius: Al3+, Mg2+, Na+, O2-. decreasing radius \rarr


A) Al3+ > Mg2+ > O2- > Na+
B) Al3+ > Mg2+ > Na+ > O2-
C) Na+ > Mg2+ > Al3+ > O2-
D) O2- > Al3+ > Mg2+ > Na+
E) O2- > Na+ > Mg2+ > Al3+

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Which one of the following does not have [Xe] as its electronic configuration?


A) Te2-
B) I-
C) Cs+
D) Ba2+
E) Sn4+

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Which of the atoms listed below has the largest radius?


A) Cl
B) I
C) P
D) Sb
E) Se

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