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Determine the equilibrium constant, Keq, at 25°C for the reaction 2Br- (aq) + I2(s) Determine the equilibrium constant, K<sub>eq</sub>, at 25°C for the reaction 2Br<sup>- </sup>(aq) + I<sub>2</sub>(s)    <sub> </sub> Br<sub>2</sub>(l) + 2I<sup>- </sup>(aq)  A) 5.7 × 10<sup>-1</sup><sup>9</sup> B) 18.30 C) 1.7 × 10<sup>54</sup> D) 1.9 × 10<sup>18</sup> E) 5.7 × 10<sup>-55</sup> Br2(l) + 2I- (aq)


A) 5.7 × 10-19
B) 18.30
C) 1.7 × 1054
D) 1.9 × 1018
E) 5.7 × 10-55

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Which of the following is true concerning a galvanic cell?


A) Reduction occurs at the anode and is where anions move towards
B) Reduction occurs at the cathode and is where anions move towards
C) Reduction occurs at the cathode and is where cations move towards
D) Oxidation occurs at the anode and is where cations move towards
E) Oxidation occurs at the cathode and is where cations move towards

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Suppose the reaction Pb(s) + 2H+(aq) \rarr Pb2+(aq) + H2(g) is carried out at pH = 4.00 and at a hydrogen gas pressure of 1.00 atm.The concentration of lead(II) ions that causes this reaction to be at equilibrium is


A) 2.5 M
B) 1.6 × 10-2 M
C) 2.5 × 10-4 M
D) 1.6 × 10-6 M
E) 0.40 M

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The electrochemical cell that utilizes the reaction Zn + Cu2+ (1 M) \rarr Zn2+ (1 M)+ Cu will have a lower cell emf when the concentrations of Zn2+ and Cu2+ ions are decreased to 0.1 M.

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Calculate Δ\Delta G° for the electrochemical cell Pb(s) | Pb2+(aq) || Fe3+(aq) | Fe2+(aq) | Pt(s)


A) -1.2 x 102 kJ/mol
B) -1.7 x 102 kJ/mol
C) 1.7 x 102 kJ/mol
D) -8.7 x 101 kJ/mol
E) -3.2 x 105 kJ/mol

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An electrochemical cell based on the following reaction has a standard cell voltage (E°cell) of 0.48 V: Sn(s) + Cu2+(aq) \rarr Sn2+(aq) + Cu(s) What is the standard reduction potential of tin(II) ? (E°(Cu2+/Cu) = 0.34 V)


A) -0.14 V
B) 0.14 V
C) -0.82 V
D) 0.82 V
E) none of these

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When a solution of a certain gadolinium salt is electrolyzed with a current of 1.0 A for 2.0 h, 0.025 mol of Gd metal forms.Calculate the charge on the gadolinium ion in the salt.

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Write the formula of the strongest oxidizing agent.given the following standard reduction potentials in acid solution Write the formula of the strongest oxidizing agent.given the following standard reduction potentials in acid solution

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A balanced redox equation must have which of the following: I.The same number of each type of atom on both sides of the equation II.The total number electrons lost in the oxidation equal to total number of electrons gained in the reduction III.The same total charge of all ionic species on both sides of the reaction IV.H2O present as a product or a reactant


A) I, II, and III
B) I and II
C) I, III, and IV
D) I, II, III, and IV
E) III and IV

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Complete and balance the following redox equation that occurs in acidic solution using the set of smallest whole-number coefficients.What is the sum of all the coefficients in the equation? PbO2(s) + Cl- \rarr Pb2+ + Cl2(g) (acidic solution)


A) 2
B) 4
C) 5
D) 9
E) 11

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If the measured voltage of the cell Zn(s) | Zn2+(aq) || Ag+(aq) | Ag(s) is 1.37 V when the concentration of Zn2+ ion is 0.010 M, what is the Ag+ ion concentration?


A) 2.5 M
B) 4.0 × 10-9 M
C) 6.2 × 10-3 M
D) 2.6 × 10-51 M
E) 6.2 × 10-5 M

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Consider the following standard reduction potentials in acid solution: Consider the following standard reduction potentials in acid solution:   The strongest oxidizing agent listed above is A) Cr<sup>3+</sup>. B) Cr. C) Mn<sup>2+</sup>. D) Co<sup>2+</sup>. E) MnO<sub>4</sub><sup>-</sup>. The strongest oxidizing agent listed above is


A) Cr3+.
B) Cr.
C) Mn2+.
D) Co2+.
E) MnO4-.

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Consider a Galvanic cell constructed from the following half cells, linked by an external circuit and by a KCl salt bridge. - an Al(s) electrode in 1.0 M Al(NO3) 3 solution - a Pb(s) electrode in 1.0 M Pb(NO3) 2 solution The balanced overall (net) cell reaction is


A) Pb(s) + Al3+(aq) \rarr Pb2+(aq) + Al(s.)
B) 3Pb(s) + 2Al3+(aq) \rarr 3Pb2+(aq) + 2Al(s) .
C) 3Pb2+(aq) + 2Al(s) \rarr 3Pb(s) + 2Al3+(aq) .
D) Pb2+(aq) + Al(s) \rarr Pb(s) + Al3+(aq) .

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Consider an electrochemical cell based on the spontaneous reaction 2AgCl(s) + Zn(s) \rarr 2Ag(s) + 2Cl- + Zn2+. If the zinc ion concentration is kept constant at 1 M, and the chlorine ion concentration is decreased from 1 M to 0.001 M, the cell voltage should


A) increase by 0.06 V.
B) increase by 0.18 V.
C) decrease by 0.06 V.
D) decrease by 0.18 V.
E) increase by 0.35 V.

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What concentration of Ni2+ ion remains in solution after electrolysis of 100.mL of 0.250 M NiSO4 solution when using a current of 2.40 amperes for 30.0 minutes? Assume Ni metal is plated out.

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The half-reaction that occurs at the cathode during electrolysis of an aqueous sodium iodide solution is


A) Na+ + e- \rarr Na.
B) Na \rarr Na+ + e-.
C) 2H2O + 2e- \rarr H2 + 2OH-.
D) I2 + 2e- \rarr 2I-.
E) 2I- \rarr I2 + 2e-.

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Calculate Δ\Delta G° (kJ/mol)for the following electrochemical cell: Cd(s)| Cd2+(aq)|| Ni2+(aq)| Ni(s)

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Calculate the minimum voltage required for the electrolysis of 1.0 M NaCl in neutral solution. 2H2O + 2Cl- (1.0 M) \rarr H2(1 atm) + Cl2(1 atm) + 2OH- (1 × 10-7 M)


A) 2.19 V
B) 1.78 V
C) 0.41 V
D) -0.41 V
E) -1.78 V

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Write the balanced overall redox equation for the following cell diagram: Pt(s)| Cu+(aq)| Cu2+(aq)|| Br2(l)| Br-(aq)| Pt(s)

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2Cu+(aq)+ B...

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Complete and balance the following redox equation.What is the coefficient of H2O when the equation is balanced with the set of smallest whole-number coefficients? H2O + MnO4- + I- \rarr MnO2 + IO3- (basic solution)


A) 1
B) 2
C) 4
D) 10
E) None of these.

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