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If a reaction is endothermic, __________ the reaction temperature results in an increase in K.

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Nitrosyl bromide decomposes according to the following equation. 2NOBr (g) Nitrosyl bromide decomposes according to the following equation. 2NOBr (g)    2NO (g) + Br<sub>2</sub> (g)  A sample of NOBr (0.64 mol) was placed in a 1.00-L flask containing no NO or Br<sub>2</sub>. At equilibrium the flask contained 0.36 mol of NOBr. How many moles of NO and Br<sub>2</sub>, respectively, are in the flask at equilibrium? A) .28,.28 B) .36,.18 C) .28,.14 D) .14,.23 E) .36,.36 2NO (g) + Br2 (g) A sample of NOBr (0.64 mol) was placed in a 1.00-L flask containing no NO or Br2. At equilibrium the flask contained 0.36 mol of NOBr. How many moles of NO and Br2, respectively, are in the flask at equilibrium?


A) .28,.28
B) .36,.18
C) .28,.14
D) .14,.23
E) .36,.36

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Given the following reaction at equilibrium at 450.0°C: CaCO3 (s) Given the following reaction at equilibrium at 450.0°C: CaCO<sub>3</sub> (s)    CaO (s) + CO<sub>2</sub> (g)  If pCO<sub>2</sub> = 0.0135 atm, K<sub>c</sub> = __________. A) 135 B) 0.0821 C) 0.801 D) 2.27 × 10<sup>-4</sup> E) 8.01 CaO (s) + CO2 (g) If pCO2 = 0.0135 atm, Kc = __________.


A) 135
B) 0.0821
C) 0.801
D) 2.27 × 10-4
E) 8.01

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In an exothermic equilibrium reaction, increasing the reaction temperature favors the formation of reactants.

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The reaction below is exothermic: 2SO2 (g) + O2 (g) The reaction below is exothermic: 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)    2SO<sub>3</sub> (g)  Le Châtelier's Principle predicts that __________ will result in an increase in the number of moles of SO<sub>3</sub> (g) in the reaction container. A) increasing the pressure B) decreasing the pressure C) increasing the temperature D) removing some oxygen E) increasing the volume of the container 2SO3 (g) Le Châtelier's Principle predicts that __________ will result in an increase in the number of moles of SO3 (g) in the reaction container.


A) increasing the pressure
B) decreasing the pressure
C) increasing the temperature
D) removing some oxygen
E) increasing the volume of the container

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The equilibrium constant for the gas phase reaction 2NH3 (g) The equilibrium constant for the gas phase reaction 2NH<sub>3</sub> (g)    N<sub>2</sub> (g) + 3H<sub>2</sub> (g)  Is K<sub>eq</sub> = 230 at 300°C. At equilibrium, __________. A) products predominate B) reactants predominate C) roughly equal amounts of products and reactants are present D) only products are present E) only reactants are present N2 (g) + 3H2 (g) Is Keq = 230 at 300°C. At equilibrium, __________.


A) products predominate
B) reactants predominate
C) roughly equal amounts of products and reactants are present
D) only products are present
E) only reactants are present

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The Keq for the equilibrium below is 0.112 at 700.0°C. SO2 (g) + The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? SO<sub>3</sub> (g)    SO<sub>2</sub> (g) +   O<sub>2</sub> (g)  A) 0.224 B) 0.0125 C) 0.112 D) 8.93 E) -0.112 O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? SO<sub>3</sub> (g)    SO<sub>2</sub> (g) +   O<sub>2</sub> (g)  A) 0.224 B) 0.0125 C) 0.112 D) 8.93 E) -0.112 SO3 (g) What is the value of Keq at this temperature for the following reaction? SO3 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? SO<sub>3</sub> (g)    SO<sub>2</sub> (g) +   O<sub>2</sub> (g)  A) 0.224 B) 0.0125 C) 0.112 D) 8.93 E) -0.112 SO2 (g) + The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? SO<sub>3</sub> (g)    SO<sub>2</sub> (g) +   O<sub>2</sub> (g)  A) 0.224 B) 0.0125 C) 0.112 D) 8.93 E) -0.112 O2 (g)


A) 0.224
B) 0.0125
C) 0.112
D) 8.93
E) -0.112

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The Keq for the equilibrium below is 0.112 at 700.0°C. SO2 (g) + The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2 </sub>(g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>3</sub> (g)    2SO<sub>2</sub> (g) + O<sub>2</sub> (g)  A) 79.7 B) 2.99 C) 17.86 D) 4.46 E) 8.93 O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2 </sub>(g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>3</sub> (g)    2SO<sub>2</sub> (g) + O<sub>2</sub> (g)  A) 79.7 B) 2.99 C) 17.86 D) 4.46 E) 8.93 SO3 (g) What is the value of Keq at this temperature for the following reaction? 2SO3 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0°C. SO<sub>2</sub> (g) +   O<sub>2 </sub>(g)    SO<sub>3</sub> (g)  What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>3</sub> (g)    2SO<sub>2</sub> (g) + O<sub>2</sub> (g)  A) 79.7 B) 2.99 C) 17.86 D) 4.46 E) 8.93 2SO2 (g) + O2 (g)


A) 79.7
B) 2.99
C) 17.86
D) 4.46
E) 8.93

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The equilibrium-constant expression for the reaction Ti (s) + 2Cl2 (g) The equilibrium-constant expression for the reaction Ti (s) + 2Cl<sub>2 </sub>(g)    TiCl<sub>4 </sub>(l)  Is given by A)    B)    C)    D) [Cl<sub>2</sub> (g) ]<sup>-2 </sup> E)   TiCl4 (l) Is given by


A) The equilibrium-constant expression for the reaction Ti (s) + 2Cl<sub>2 </sub>(g)    TiCl<sub>4 </sub>(l)  Is given by A)    B)    C)    D) [Cl<sub>2</sub> (g) ]<sup>-2 </sup> E)
B) The equilibrium-constant expression for the reaction Ti (s) + 2Cl<sub>2 </sub>(g)    TiCl<sub>4 </sub>(l)  Is given by A)    B)    C)    D) [Cl<sub>2</sub> (g) ]<sup>-2 </sup> E)
C) The equilibrium-constant expression for the reaction Ti (s) + 2Cl<sub>2 </sub>(g)    TiCl<sub>4 </sub>(l)  Is given by A)    B)    C)    D) [Cl<sub>2</sub> (g) ]<sup>-2 </sup> E)
D) [Cl2 (g) ]-2
E) The equilibrium-constant expression for the reaction Ti (s) + 2Cl<sub>2 </sub>(g)    TiCl<sub>4 </sub>(l)  Is given by A)    B)    C)    D) [Cl<sub>2</sub> (g) ]<sup>-2 </sup> E)

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Given the following reaction at equilibrium, if Kc = 1.90 × 1019 at 25.0°C, Kp = __________. H2 (g) + Br2 (g) Given the following reaction at equilibrium, if K<sub>c</sub> = 1.90 × 10<sup>19 </sup>at 25.0°C, K<sub>p</sub> = __________. H<sub>2</sub> (g) + Br<sub>2</sub> (g)    2 HBr (g)  A) 5.26 × 10<sup>-20</sup> B) 1.56 × 10<sup>4</sup> C) 6.44 × 10<sup>5</sup> D) 1.90 × 10<sup>19</sup> E) none of the above 2 HBr (g)


A) 5.26 × 10-20
B) 1.56 × 104
C) 6.44 × 105
D) 1.90 × 1019
E) none of the above

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Dinitrogen tetroxide partially decomposes according to the following equilibrium: N2O4 (g) Dinitrogen tetroxide partially decomposes according to the following equilibrium: N<sub>2</sub>O<sub>4</sub> (g)    2NO<sub>2</sub> (g)  A 1.000-L flask is charged with 3.00 × 10<sup>-2</sup> mol of N<sub>2</sub>O<sub>4</sub>. At equilibrium, 2.36 × 10<sup>-2</sup> mol of N<sub>2</sub>O<sub>4</sub> remains. K<sub>eq</sub> for this reaction is __________. A) 0.723 B) 0.391 C) 0.212 D) 6.94 × 10<sup>-3</sup> E) 1.92 × 10<sup>-4</sup> 2NO2 (g) A 1.000-L flask is charged with 3.00 × 10-2 mol of N2O4. At equilibrium, 2.36 × 10-2 mol of N2O4 remains. Keq for this reaction is __________.


A) 0.723
B) 0.391
C) 0.212
D) 6.94 × 10-3
E) 1.92 × 10-4

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D

Which of the following expressions is the correct equilibrium-constant expression for the reaction below? HF (aq) + H2O (l) Which of the following expressions is the correct equilibrium-constant expression for the reaction below? HF (aq) + H<sub>2</sub>O (l)    H<sub>3</sub>O<sup>+</sup> (aq) + F<sup>-</sup> (aq)  A) [HF][H<sub>2</sub>O] / [H<sub>3</sub>O<sup>+</sup>][F<sup>-</sup>] B) 1 / [HF] C) [H<sub>3</sub>O<sup>+</sup>][F<sup>-</sup>] / [HF][H<sub>2</sub>O] D) [H<sub>3</sub>O<sup>+</sup>][F<sup>-</sup>] / [HF] E) [F<sup>-</sup>] / [HF] H3O+ (aq) + F- (aq)


A) [HF][H2O] / [H3O+][F-]
B) 1 / [HF]
C) [H3O+][F-] / [HF][H2O]
D) [H3O+][F-] / [HF]
E) [F-] / [HF]

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Which one of the following is true concerning the Haber process?


A) It is a process used for shifting equilibrium positions to the right for more economical chemical synthesis of a variety of substances.
B) It is a process used for the synthesis of ammonia.
C) It is another way of stating Le Châtelier's principle.
D) It is an industrial synthesis of sodium chloride that was discovered by Karl Haber.
E) It is a process for the synthesis of elemental chlorine.

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B

If Reaction A + Reaction B = Reaction C, then Kc Reaction C = __________.

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Kc Reaction ...

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For an exothermic reaction, increasing the reaction temperature results in a(an)__________ in K.

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Le Châtelier's principle states that if a system at equilibrium is disturbed, the equilibrium will shift to minimize the disturbance.

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True

At 27°C, Kp = 0.095 for the equilibrium: NH4HS (s) At 27°C, K<sub>p</sub> = 0.095 for the equilibrium: NH<sub>4</sub>HS (s)    NH<sub>3 </sub>(g) + H<sub>2</sub>S (g)  A sample of solid NH<sub>4</sub>HS is placed in a closed vessel and allowed to equilibrate. Calculate the equilibrium partial pressure (atm) of ammonia, assuming that some solid NH<sub>4</sub>HS remains. A) 0.31 B) 0.095 C) 0.052 D) 0.0049 E) 3.8 NH3 (g) + H2S (g) A sample of solid NH4HS is placed in a closed vessel and allowed to equilibrate. Calculate the equilibrium partial pressure (atm) of ammonia, assuming that some solid NH4HS remains.


A) 0.31
B) 0.095
C) 0.052
D) 0.0049
E) 3.8

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Consider the following reaction at equilibrium: 2SO2 (g) + O2 (g) Consider the following reaction at equilibrium: 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)    2SO<sub>3</sub> (g) ΔH° = -99 kJ Le Châtelier's principle predicts that an increase in temperature will result in __________. A) a decrease in the partial pressure of SO<sub>3</sub> B) a decrease in the partial pressure of SO<sub>2</sub> C) an increase in K<sub>eq</sub> D) no changes in equilibrium partial pressures E) the partial pressure of O<sub>2</sub> will decrease 2SO3 (g) ΔH° = -99 kJ Le Châtelier's principle predicts that an increase in temperature will result in __________.


A) a decrease in the partial pressure of SO3
B) a decrease in the partial pressure of SO2
C) an increase in Keq
D) no changes in equilibrium partial pressures
E) the partial pressure of O2 will decrease

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Consider the following reaction at equilibrium: 2CO2 (g) Consider the following reaction at equilibrium: 2CO<sub>2</sub> (g)    2CO (g) + O<sub>2</sub> (g) ΔH° = -514 kJ Le Châtelier's principle predicts that adding O<sub>2</sub> (g) to the reaction container will __________. A) increase the partial pressure of CO (g) at equilibrium B) decrease the partial pressure of CO<sub>2</sub> (g) at equilibrium C) increase the value of the equilibrium constant D) increase the partial pressure of CO<sub>2</sub> (g) at equilibrium E) decrease the value of the equilibrium constant 2CO (g) + O2 (g) ΔH° = -514 kJ Le Châtelier's principle predicts that adding O2 (g) to the reaction container will __________.


A) increase the partial pressure of CO (g) at equilibrium
B) decrease the partial pressure of CO2 (g) at equilibrium
C) increase the value of the equilibrium constant
D) increase the partial pressure of CO2 (g) at equilibrium
E) decrease the value of the equilibrium constant

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The equilibrium constant (Kp) for the interconversion of PCl5 and PCl3 is 0.0121: PCl5 (g) The equilibrium constant (K<sub>p</sub>) for the interconversion of PCl<sub>5</sub> and PCl<sub>3</sub> is 0.0121: PCl<sub>5</sub> (g)    PCl<sub>3</sub> (g) + Cl<sub>2</sub> (g)  A vessel is charged with PCl<sub>5</sub>, giving an initial pressure of 0.123 atm. At equilibrium, the partial pressure of PCl<sub>3</sub> is __________ atm. A) 0.0782 B) 0.0455 C) 0.0908 D) 0.0330 E) 0.123 PCl3 (g) + Cl2 (g) A vessel is charged with PCl5, giving an initial pressure of 0.123 atm. At equilibrium, the partial pressure of PCl3 is __________ atm.


A) 0.0782
B) 0.0455
C) 0.0908
D) 0.0330
E) 0.123

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