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Which of the following concentration units are temperature dependent?


A) mole fraction
B) molality
C) mass percent
D) molarity
E) None of the above

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A solution is prepared by dissolving 40.0 g of sucrose,C12H22O11,in 250.g of water at 25 °C.What is the vapour pressure of the solution if the vapour pressure of water at 25 °C is 23.76 mmHg?


A) 0.198 mmHg
B) 20.5 mmHg
C) 23.6 mmHg
D) 24.0 mmHg

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C

Calculate the molality of a solution formed by dissolving 27.8 g of LiI in 500.0 mL of water.


A) 0.254 mol kg-1
B) 0.394 mol kg-1
C) 0.556 mol kg-1
D) 0.241 mol kg-1
E) 0.415 mol kg-1

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Choose the aqueous solution below with the lowest freezing point.These are all solutions of nonvolatile solutes and you should assume ideal van't Hoff factors where applicable.


A) 0.075 mol kg-1 NaI
B) 0.075 mol kg-1 (NH4) 3PO4
C) 0.075 mol kg-1 NaBrO4
D) 0.075 mol kg-1 LiCN
E) 0.075 mol kg-1 KNO2

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Which of the following defines dynamic equilibrium of a solution?


A) rate of dissolution = rate of deposition
B) rate of dissolution < rate of deposition
C) rate of dissolution > rate of deposition
D) rate of bubbling > rate of dissolving
E) rate of evaporating > rate of condensing

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What happens to a supersaturated solution of potassium acetate once it is cooled and a small crystal of solid potassium acetate is added?

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The portion of potassium aceta...

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Calculate the freezing point of a solution of 40.0 g salicylaldehyde,C7H6O2,dissolved in 800.g of benzene,C6H6. Kf for benzene is 5.10Cm1 5.10^{\circ} \mathrm{C} \mathrm{m}^{-1} and the freezing point is 5.50 °C for benzene.


A) -2.09 °C
B) 2.09 °C
C) 3.41 °C
D) 7.59 °C

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Calculate the mass of maltose,C12H22O11,contained in 725.0 mL of solution if the measured vapour pressure of the solution is 41.6 mbar at 30 °C.The vapour pressure of pure water at 30 °C is 42.40 mbar; assume no change in volume occurs upon dissolution.


A) 482 g
B) 329 g
C) 265 g
D) 163 g
E) 94.1 g

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What is the term for the amount of solute in moles per kilogram of solvent?


A) molality
B) molarity
C) mole fraction
D) mole percent
E) mass percent

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What volume of 3.00 mol L-1 CH3OH solution is needed to provide 0.220 mol of CH3OH?


A) 1.52 mL
B) 13.6 mL
C) 73.3 mL
D) 660 mL

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A solution of LiCl in water has XLiCl = 0.0900.What is the molality?


A) 4.46 mol kg-1 LiCl
B) 5.00 mol kg-1 LiCl
C) 5.49 mol kg-1 LiCl
D) 9.89 mol kg-1 LiCl

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A 1.00 L sample of water contains 0.0036 g of Cl- ions.Determine the concentration of chloride ions in ppm if the density of the solution is 1.00 g mL-1.


A) 2.8 ppm
B) 7.2 ppm
C) 3.6 ppm
D) 1.8 ppm
E) 5.4 ppm

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What is the mole fraction of oxygen in a gas mixture that is 37% oxygen and 63% nitrogen by volume?


A) 0.34
B) 0.37
C) 0.25
D) 0.52

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An unknown nonelectrolyte and nonvolatile compound is dissolved in enough pure water to make 229 mL of solution.The vapour pressure above the solution drops from 233.7 Torr to 229.1 Torr when 82.3 g of the compound is dissolved at constant temperature.Determine the molar mass of the unknown compound.Assume no change in volume occurs upon dissolution.


A) 323 g mol-1
B) 480 g mol-1
C) 414 g mol-1
D) 459 g mol-1
E) 508 g mol-1

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A

Calculate the osmotic pressure,in bar,of a solution containing 3.00 mg of a sugar (342 g mol-1)in 15.0 mL of water at 25 °C.

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What is the term for the amount of solute in moles per litre of solution?


A) molality
B) molarity
C) mole fraction
D) mole percent
E) mass percent

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Define osmosis.

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Osmosis is the flow of solvent...

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At 20 °C,an aqueous solution that is 24.0% by mass in ammonium chloride has a density of 1.0674 gmL1\mathrm { g } \mathrm { mL } ^ { - 1 } What is the molarity of ammonium chloride in the solution? The formula weight of NH4\mathrm { NH } _ { 4 } Cl is 53.50 g mol153.50 \mathrm {~g} \mathrm {~mol} ^ { - 1 }


A) 0.209 mol L-1
B) 0.0445 mol L-1
C) 22.5 mol L-1
D) 0.479 mol L-1
E) 4.79 mol L-1

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A KCl solution is prepared by dissolving 25.0 g KCl in 250.0 g of water at 25 °C.What is the vapour pressure of the solution if the vapour pressure of water at 25 °C is 23.76 mmHg?


A) 21.6 mmHg
B) 22.7 mmHg
C) 23.2 mmHg
D) 24.9 mmHg

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B

Choose the situation below that would result in an endothermic ?solutionH.


A) when Δsolute H|\Delta _ { \text {solute } } H \mid > Δ hydration H|\Delta \text { hydration } H \mid
B) when Δsolute H<Δhydration H\left| \Delta _ { \text {solute } } H \right| < \left| \Delta _ { \text {hydration } } H \right|
C) when Δsolute H is close to Δhydration H\left| \Delta _ { \text {solute } } H \right| \text { is close to } \left| \Delta _ { \text {hydration } } H \right|
D) when Δsolvent H>Δsolute H\left| \Delta _ { \text {solvent } } H \right| > \left| \Delta _ { \text {solute } } H \right|
E) There isn't enough information to determine the answer.

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