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Which of the following are the products of a homolytic cleavage of a C-C bond of ethane?


A) Which of the following are the products of a homolytic cleavage of a C-C bond of ethane?  A)    B)    C)    D)
B) Which of the following are the products of a homolytic cleavage of a C-C bond of ethane?  A)    B)    C)    D)
C) Which of the following are the products of a homolytic cleavage of a C-C bond of ethane?  A)    B)    C)    D)
D) Which of the following are the products of a homolytic cleavage of a C-C bond of ethane?  A)    B)    C)    D)

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Upon treatment with NBS and irradiation with UV light, 2-isopropyl-3-methyl-1-butene reacts to produce exactly two monobrominated compounds. Draw the products of this reaction.

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Which of the following are possible product(s) of the reaction shown? Which of the following are possible product(s)  of the reaction shown?   A)  I B)  I, II C)  I, II, IV, V D)  I, III, IV, V E)  I, II, III, IV, IV


A) I
B) I, II
C) I, II, IV, V
D) I, III, IV, V
E) I, II, III, IV, IV

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Which term most accurately describes the process shown below? Which term most accurately describes the process shown below?   A)  coupling B)  proton transfer C)  halogen abstraction D)  hydrogen abstraction E)  homolytic cleavage


A) coupling
B) proton transfer
C) halogen abstraction
D) hydrogen abstraction
E) homolytic cleavage

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Upon treatment with NBS and irradiation with UV light, 2-methyl-2-butene reacts to produce exactly six monobrominated compounds. Draw the products of this reaction.

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Use correct arrow formalism consistent with the following radical process: Use correct arrow formalism consistent with the following radical process:

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Propose an efficient synthesis of 2-butyn-1-ol from propane.

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Which term most accurately describes the process shown below?  Which term most accurately describes the process shown below?   A)  coupling B)  hydrogen abstraction C)  halogen abstraction D)  homolytic cleavage E)  addition to a  \pi  bond


A) coupling
B) hydrogen abstraction
C) halogen abstraction
D) homolytic cleavage
E) addition to a π\pi bond

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Predict the product(s) of the following reaction: Predict the product(s)  of the following reaction:   A)  I B)  II C)  III D)  I, II E)  I, II, III, IV


A) I
B) II
C) III
D) I, II
E) I, II, III, IV

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Of the four choices shown, which is likely to be a major product of the reaction below? Of the four choices shown, which is likely to be a major product of the reaction below?   A)  I B)  II C)  III D)  IV


A) I
B) II
C) III
D) IV

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One possible product of thermal cracking of hexane is 1-butene. Use correct arrow formalism to suggest a possible mechanism for this process starting from an alkyl radical.

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Predict the major product(s) of the reaction shown below: Predict the major product(s)  of the reaction shown below:   A)  I B)  II C)  III D)  IV E)  II and III


A) I
B) II
C) III
D) IV
E) II and III

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Using correct arrow formalism, draw all of the reasonable resonance structures for the radical shown below. Using correct arrow formalism, draw all of the reasonable resonance structures for the radical shown below.

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Which of the following is most reactive towards chlorination?


A) methane
B) chloromethane
C) dichloromethane
D) chloroform
E) ethane

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Use correct arrow formalism to show the mechanism of the following radical process: Use correct arrow formalism to show the mechanism of the following radical process:

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Both compounds A and B have molecular formula C6H14. Monochlorination of compound A results in formation of two constitutional isomers. Monochlorination of compound B results in formation of four constitutional isomers. Identify compounds A and B, and show the products of each monochlorination.

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Use correct arrow formalism to show the propagation steps for the autooxidation of diethyl ether.

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Which of the following is the correct name for the major product of the following reaction? Which of the following is the correct name for the major product of the following reaction?   A)  (R) -3-bromo-3-ethylbutane B)  (S) -3-bromo-3-ethylbutane C)  (R) -3-bromo-3-methylpentane D)  (S) -3-bromo-3-methylpentane E)  3-bromo-3-methylpentane


A) (R) -3-bromo-3-ethylbutane
B) (S) -3-bromo-3-ethylbutane
C) (R) -3-bromo-3-methylpentane
D) (S) -3-bromo-3-methylpentane
E) 3-bromo-3-methylpentane

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Propose an efficient synthesis of polyethylene from ethane.

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The free radical polymerization of styrene with benzoyl peroxide yields a polymer that has repeat units arranged primarily in a 'head-to-tail' arrangement. This means that the phenyl group primarily ends up placed at alternating carbon atoms along the chain. Use correct arrow formalism to show why this arrangement is preferred over a 'head-to-head' or 'tail-to-tail' arrangement. The free radical polymerization of styrene with benzoyl peroxide yields a polymer that has repeat units arranged primarily in a 'head-to-tail' arrangement. This means that the phenyl group primarily ends up placed at alternating carbon atoms along the chain. Use correct arrow formalism to show why this arrangement is preferred over a 'head-to-head' or 'tail-to-tail' arrangement.

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The 'head-to-tail' addition gi...

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