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According to valence bond theory,the triple bond in ethyne (acetylene,C2H2) consists of


A) three σ bonds and no π bonds.
B) two σ bonds and one π bond.
C) one σ bond and two π bonds.
D) no σ bonds and three π bonds.
E) one σ bond,one π bond,and one bond intermediate between σ and π.

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According to the VSEPR model,the molecular geometry of the carbonate ion,CO32-,is


A) square planar.
B) tetrahedral.
C) pyramidal.
D) trigonal planar.
E) octahedral.

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How many π bonds are there in CH3COCH3?

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The bond angle for an sp hybrid orbital is smaller than the bond angle for an sp2 hybrid orbital.

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What is the molecular geometry of SiF62- as predicted by the VSEPR model? What is the molecular geometry of SiF<sub>6</sub><sup>2-</sup> as predicted by the VSEPR model?   A) trigonal bipyramidal B) octahedral C) tetrahedral D) seesaw E) square pyramidal


A) trigonal bipyramidal
B) octahedral
C) tetrahedral
D) seesaw
E) square pyramidal

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What is the hybridization of phosphorus in PCl3?


A) sp3
B) sp2
C) sp
D) sp3d
E) sp3d2

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For a homonuclear diatomic molecule,which molecular orbital is the highest in energy?


A) For a homonuclear diatomic molecule,which molecular orbital is the highest in energy? A)    B)    C)    D)    E) All of these orbitals have the same energy.
B) For a homonuclear diatomic molecule,which molecular orbital is the highest in energy? A)    B)    C)    D)    E) All of these orbitals have the same energy.
C) For a homonuclear diatomic molecule,which molecular orbital is the highest in energy? A)    B)    C)    D)    E) All of these orbitals have the same energy.
D) For a homonuclear diatomic molecule,which molecular orbital is the highest in energy? A)    B)    C)    D)    E) All of these orbitals have the same energy.
E) All of these orbitals have the same energy.

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How do you describe the molecular geometry of a molecule that has more than one central atom?


A) You describe the molecular geometry around the most electronegative atom.
B) You describe the molecular geometry around each central atom separately.
C) You describe the molecular geometry around the most electropositive atom.
D) You describe the molecular geometry around the atom with the largest atomic radius.
E) You describe the molecular geometry around the atom with the largest bond angle.

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According to the VSEPR model,which molecule is predicted to be linear?


A) H2S
B) HCN
C) BF3
D) H2CO
E) SO3

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Carbon uses ______ hybrid orbitals in ClCN.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

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Which statement is not true of molecular orbitals?


A) The number of molecular orbitals formed is always equal to the number of atomic orbitals combined.
B) A molecular orbital can accommodate up to two electrons.
C) When electrons are added to orbitals of the same energy,the most stable arrangement is predicted by Hund's rule.
D) Low-energy molecular orbitals fill before high-energy molecular orbitals fill.
E) Antibonding molecular orbitals are higher in energy than all of the bonding molecular orbitals.

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When molecules that exhibit separation of charges are placed in an electric field,they become oriented positive end to negative plate and negative end to positive plate.

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For different structural arrangements of atoms having the formula XeF2Cl2,which structures represent polar molecules? (Black = Xe,Yellow = F,Green = Cl) For different structural arrangements of atoms having the formula XeF<sub>2</sub>Cl<sub>2</sub>,which structures represent polar molecules? (Black = Xe,Yellow = F,Green = Cl)    A) I and III B) II only C) I,II and III D) II and III E) None of these structures are polar.


A) I and III
B) II only
C) I,II and III
D) II and III
E) None of these structures are polar.

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In the valence bond treatment,a π bond is formed when two p orbitals overlap side to side.

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What does the abbreviation VSEPR stand for?


A) Very Specific Electron and Proton Repair
B) Variable Selective of Electron and Protons
C) Valence Shell for Every Proton
D) Very Selective Electron Pair theory
E) Valence-Shell Electron-Pair Repulsion

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In the valence bond treatment,overlap of an s orbital on one atom with an sp3 orbital on another atom gives rise to a σ bond.

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The nitrosonium ion,NO+,forms a number of interesting complexes with nickel,cobalt,and iron. According to molecular orbital theory,which statement about NO+ is correct?


A) NO+ has a bond order of 2 and is paramagnetic.
B) NO+ has a bond order of 2 and is diamagnetic.
C) NO+ has a bond order of 3 and is paramagnetic.
D) NO+ has a bond order of 3 and is diamagnetic.
E) NO+ has a bond order of 2.5 and is neither paramagnetic nor diamagnetic.

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According to the VSEPR model,which molecule has a predicted tetrahedral molecular geometry?


A) XeF4
B) BF3
C) AsF5
D) CF4
E) NH3

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A molecule with the formula AB3 and a trigonal planar molecular geometry uses _________ to form its σ bonds.


A) sp hybrid orbitals
B) sp2 hybrid orbitals
C) sp3 hybrid orbitals
D) sp3d hybrid orbitals
E) sp3d2 hybrid orbitals

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In one sentence state how molecular orbitals are usually obtained.

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Molecular orbitals are obtaine...

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